Speciation-Dependent Molecular Mechanism of Electron Transfer from the c-Type Cytochrome MtrC to U(VI)-Ligand Complexes

Uranium (U) is a radioactive element widely present in the environment, primarily existing in its hexavalent (U(VI)) and tetravalent (U(IV)) oxidation states. Under oxidizing conditions, U(VI) is the dominant stable form, while under reducing conditions, U(VI) can be reduced to U(IV). This reduction process can occur through abiotic pathways (e.g.,...